Chlorido(12,17-diethoxycarbonyl-11,18-dimethyl-2:3,6:7-dibutanocorrphycenato-κ4 N)iron(III)
نویسندگان
چکیده
The title complex, [Fe(C(36)H(36)N(4)O(4))Cl], shows a domed structure with a slightly distorted trapezoidpyramidal core, in which the perpendicular displacements of the Fe(III) atom from the mean pyrrole N(4) plane are 0.418 (3) and 0.465 (3) Å for the two crystallographically independent mol-ecules.
منابع مشابه
(12,17-Diethoxycarbonyl-11,18-dimethyl-2,3:6,7-dibutanocorrphycenato)copper(II)–12,17-diethoxycarbonyl-11,18-dimethyl-2:3,6:7-dibutanocorrphycene (3/97)
The corrphycene mol-ecule of the title compound, [Cu(C(36)H(36)N(4)O(4))](0.034).0.966C(36)H(38)N(4)O(4), has an essentially planar macrocyclic framwork with a slightly distorted trapezoidal N(4) core; the r.m.s. deviation of the peripheral 20 C atoms and four N atoms is 0.054 (3) Å. The surface area within the N(4)-coordinating core (8.358 Å(2)) is significantly smaller than that (8.503 Å(2)) ...
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The crystal structure of the title complex, {(C(2)H(8)N)[CuCl(2)(N(3))]}(n), exhibits inorganic chains consisting of Cu(II) cations as well azide and chloride anions. The chains, made up from Cu-Cl-Cu-N-Cu linkages, are aligned parallel to the c axis. This architecture is further stabilized by a number of N-H⋯Cl hydrogen bonds involving the protonated charge-compensating dimethyl-amine cations ...
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